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It has long been believed that aniline dyes, first synthesized in England during the 1850s and assumed to be imported into Japan during the 1860s, were responsible for the "acid" colors found in nishiki-e. Despite whatever "progress" these colors might have represented, most collectors and scholars in the West could see only a rather garish and distasteful parade of harsh reds, purples, yellows, and greens, which they believed degraded the art of ukiyo-e. Even today, many find the Meiji palette strident and an affront to their sensibilities. An illustration with the sort of color palette under discussion is shown in the image on the immediate right portraying the actor Bandô Hikosaburô V (坂東彦三郎). In 1877 (the year of Hikosaburô's death), the artist Toyohara Kunichika designed a series titled Kaika nijûshikô: (Twenty-four paragons of enlightenment: 開化廿四孝) published by Takekawa Seikichi. On full display in this print are the vibrant red, purple and yellow colorants emblematic of Meiji-period nishiki-e. With the preceding in mind, readers will discover that the standard narrative on aniline dyes has been roundly destabilized by a recent technical analysis that debunks the early assumptions regarding the aniline revolution. To be sure, vivid colors were de rigueur for a vast number of nishiki-e during Meiji, and those who have condemned the tectonic shifts in colors from pre-Meiji practice need not relinquish their dismissive judgments. Yet until 2018 (see Cesaratto et al. reference below), definitive research on the chemical nature of these colorants has been elusive. Now, however, new conclusions have been reached with the aid of surface-enhanced Raman spectroscopy (SERS) coupled with micro-Raman, X-ray fluorescence (XRF), and fiber optic reflectance spectroscopies (FORS) performed on 57 nishiki-e assembled for analysis by Professor Henry D. Smith II. To minimize damage in SERS analysis, samples were obtained by removing fragments of single paper fibers (~ 100 µm in length) already raised or partially detached from the paper surface. The remaining complementary spectroscopy techniques were non-destructive. The authors of the 2018 study presented the following summary:
A final key finding is that colorants were often combined, either through preparatory mixing or by direct mixing on the printing block, or by two-step overprinting. The authors of the 2018 study also provided the following graph to encapsulate the timeline for Meiji colorants: ![]() The story is more complex than outlined here, so readers are encouraged to review the articles cited below. Simply put, a wholly "aniline revolution" in Meiji nishiki-e production never took place, although a color revolution did indeed occur, resulting in a vivid palette overall. However, the only true aniline dye, used from 1875 until 1889, was methyl violet, which yielded a visibly stronger purple than previous red-blue mixtures. Moreover, the new nishiki-e red appearing in 1869 and long accused by many as one of the aniline culprits was actually an organic colorant, the insect dye chochineal carmine. Incidentally, a complementary study of 31 nishiki-e (issued from 1864 to 1895) was published in 2016 (ref. #3 below) confirming the work of Yamato (ref #4 below) that arsenic sulfides of synthetic origin were used widely for yellow (orpiment, in Japanese, sekiô, 石黄) and green colored areas (the latter obtained by mixing Prussian blue with yellow arsenic sulfides). The authors also concluded that the manufacture of synthetic arsenic sulfide pigments might have started in Iwashiro province in 1846. Their work provides the first conclusive evidence for the use of synthetic arsenic sulfides in woodblock prints in Japan. References for Meiji-period colorant research
Toyohara Kunichika Toyohara Kunichika (豊原國周 1835-1900) is one of the artists whose works have been closely associated with aniline dyes (to a degree that is somewhat undeserved). His first teacher was [Ichiôsai] Toyohara Chikanobu (dates unknown; personal name Toriyama Shinji), a minor artist of the Hasegawa school working in the Kanô style of painting. (This first Chikanobu should not be confused with the later and better known Chikanobu who was Kunichika's own pupil — [Yôshû] Toyohara Chikanobu, 1838-1912.) Kunichika probably joined the studio of Utagawa Kunisada (1786-1865) around 1848 when he was 13 years of age, and he ultimately achieved a high ranking within the Utagawa studio. After the death of Kunisada, Kunichika went on to become the most important designer of actor prints during the Meiji period, while also producing many bijin-ga ("pictures of beautiful women"). He was a prolific artist, one of the last masters of ukiyo-e printmaking. The print shown immediately to the right is a good example of Meiji-period colorants used in a restrained manner. The design was published by Takegawa Seikichi for the series Junshoku sanjûroku kasen (Thirty-six charming colors of selected beautiful women: 潤色三十六花撰). Dated 1881, the print also names the block carver ("Gin"). The saturated purples and reds in this design might startle us with their saturated bright intensity, but, on the whole, the colors have been used sparingly and to positive advantage, serving the purpose of signifying elegance and fashionable modernity. ©2000-2020 by John Fiorillo BIBLIOGRAPHY
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